You did not need to solve the integral. The submerged volume is a spherical cap, the volume of which is pi*h2*(3r-h)/3, where h is the height of the sphere from the intersecting plane. In your diagram, this is (R+s). For the more general case this is 5 - (r/sin(t) - r), or (1-1/sin(t))r + 5. Now, after some review of the derivative, which I was barely introduced to some 14 years ago, I have a complete solution for the question as posted.
f(r) = pi/3 * h2 * (3r-h)
h = (1-1/sin(15)*r + 5; letting n be the constant value (1-1/sin(15)), we have h=nr+5, then:
f(r) = pi/3 * (nr+5)2 * (3r-nr-5)
f(r) = pi/3 * ((3n2-n3)r3 + (30n-15n2)r2 + (75-75n)r - 125)
f'(r) = pi/3 * (3(3n2-n3)r2 + 2(30n-15n2)r + (75-75n))
f'(r) = pi * ((3n2-n3)r2 + (20n-10n2)r + (25-25n))
(3n2-n3)r2 + (20n-10n2)r + (25-25n) = 0
The radical cleans up nicely, giving us (-b + 10n)/2a and (-b - 10n)/2a
(-b + 10n)/2a evaluates to 1.74599, which is 5 * sin(15) / (1- sin(15)), where the sphere just touches the surface of the water, giving a submerged volume of 0.
(-b - 10n)/2a evaluates to 5*sin(15)/(1+sin(15)+2*sin2(15)) = 1.150465939351, giving a submerged volume of 5.3177342075568337849950 cubic inches.